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<h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Rubidiumhyperoxid</span></h1>
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<div id="mw-content-text" class="mw-body-content mw-content-ltr" lang="de" dir="ltr"><div class="mw-content-ltr mw-parser-output" lang="de" dir="ltr"><table class="wikitable infobox float-right" id="Vorlage_Infobox_Chemikalie" style="font-size:90%; margin-top:0; width:350px;" summary="Infobox Chemikalie">

<tbody><tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Kristallstruktur
</th></tr>
<tr>
<td colspan="2" class="hintergrundfarbe-basis" style="text-align:center;"><span typeof="mw:File"></span>
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<tr>
<td colspan="2" style="text-align:center; font-size:80%;"><span style="background:#C0C0C0;border-radius: 12px;color: transparent; width: 12px; line-height:12px;display:inline-block;">_</span> <a href="Rubidium" title="Rubidium">Rb</a><sup>+</sup> <span style="visibility:hidden;">0</span> <span style="background:#FF0000;border-radius: 12px;color: transparent; width: 12px; line-height:12px;display:inline-block;">_</span>–<span style="background:#FF0000;border-radius: 12px;color: transparent; width: 12px; line-height:12px;display:inline-block;">_</span> <a href="Sauerstoff" title="Sauerstoff">[O–O]</a><sup>−</sup>
</td></tr>








<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Allgemeines
</th></tr>
<tr>
<td style="width:33%;">Name
</td>
<td>Rubidiumhyperoxid
</td></tr>
<tr>
<td>Andere Namen
</td>
<td>
<ul><li>Rubidiumdioxid</li>
<li>Rubidiumsuperoxid (veraltet)</li></ul>
</td></tr>
<tr>
<td><a href="Verh%C3%A4ltnisformel" title="Verhältnisformel">Verhältnisformel</a>
</td>
<td>RbO<sub>2</sub>
</td></tr>
<tr>
<td>Kurzbeschreibung
</td>
<td>
<p>oranger, kristalliner Feststoff<sup id="cite_ref-webelements_1-0" class="reference"><a href="#cite_note-webelements-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Externe Identifikatoren/Datenbanken
</th></tr>
<tr>
<td colspan="2" style="padding:0;">
<table class="mw-collapsible mw-collapsed wikitable" data-expandtext="+" data-collapsetext="−" style="border-top:none; margin:-1px; width:calc(100% + 2px);">

<tbody><tr>
<td style="width:33%;"><a href="CAS-Nummer" title="CAS-Nummer">CAS-Nummer</a>
</td>
<td><span title="Untervorlage eingebunden: CASRN"></span><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=12137-25-6">12137-25-6</a><span class="editoronly" style="display:none;"></span>
</td>
<td style="background:#FFDEAD; color:#202122; border-top:1px solid #FFDEAD; padding:0.2em 0; vertical-align:bottom; width:5%;">
</td></tr>










<tr>
<td style="border-right:1px solid #a2a9b1;"><a href="Wikidata" title="Wikidata">Wikidata</a>
</td>
<td colspan="2"><a href="https://www.wikidata.org/wiki/Q2171592" class="extiw external" title="d:Q2171592">Q2171592</a>
</td></tr></tbody></table>
</td></tr>








<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Eigenschaften
</th></tr>
<tr>
<td><a href="Molare_Masse" title="Molare Masse">Molare Masse</a>
</td>
<td>117,47 g·<a href="Mol" title="Mol">mol</a><sup>−1</sup>
</td></tr>
<tr>
<td><a href="Aggregatzustand" title="Aggregatzustand">Aggregatzustand</a>
</td>
<td>
<p>fest<sup id="cite_ref-webelements_1-1" class="reference"><a href="#cite_note-webelements-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Dichte" title="Dichte">Dichte</a>
</td>
<td>
<p>3,0 g·cm<sup>−3</sup><sup id="cite_ref-webelements_1-2" class="reference"><a href="#cite_note-webelements-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Schmelzpunkt" title="Schmelzpunkt">Schmelzpunkt</a>
</td>
<td>
<p>412–432 °C<sup id="cite_ref-webelements_1-3" class="reference"><a href="#cite_note-webelements-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>








<tr>
<td><a href="L%C3%B6slichkeit" title="Löslichkeit">Löslichkeit</a>
</td>
<td>
<p>heftige Zersetzung in Wasser<sup id="cite_ref-brauer_2-0" class="reference"><a href="#cite_note-brauer-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>




<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Sicherheitshinweise
</th></tr>


<tr>
<td colspan="2">
<table cellspacing="0" cellpadding="2" style="width:100%;">




<tbody><tr>
<td colspan="2" style="text-align:center"><b><a href="Global_harmonisiertes_System_zur_Einstufung_und_Kennzeichnung_von_Chemikalien" title="Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien">GHS-Gefahrstoffkennzeichnung</a></b><br><i>keine Einstufung verfügbar</i><sup id="cite_ref-NV_3-0" class="reference"><a href="#cite_note-NV-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</td></tr></tbody></table>
</td></tr>












<tr>
<td colspan="2" style="background:#FFDEAD; color:#202122; font-size:80%; text-align:center; line-height:150%; padding:.25em;">Wenn nicht anders vermerkt, gelten die angegebenen Daten bei <a href="Standardbedingungen" title="Standardbedingungen">Standardbedingungen</a> (0 °C, 1000&nbsp;hPa).
</td></tr></tbody></table><p><span class="editoronly" style="display:none;"></span>
</p><p><b>Rubidiumhyperoxid</b> ist eine <a href="Chemische_Verbindung" title="Chemische Verbindung">chemische Verbindung</a> zwischen <a href="Rubidium" title="Rubidium">Rubidium</a> und <a href="Sauerstoff" title="Sauerstoff">Sauerstoff</a> aus der Gruppe der <a href="Oxid" class="mw-redirect" title="Oxid">Oxide</a>, genauer der <a href="Hyperoxid" class="mw-redirect" title="Hyperoxid">Hyperoxide</a>.
</p>

<div class="mw-heading mw-heading2"><h2 id="Gewinnung_und_Darstellung">Gewinnung und Darstellung</h2></div>
<p>Rubidiumhyperoxid bildet sich beim Verbrennen von Rubidium im Sauerstoffüberschuss.<sup id="cite_ref-Howi_4-0" class="reference"><a href="#cite_note-Howi-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>
</p>
<dl><dd><span class="mwe-math-element mwe-math-element-inline"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \mathrm {Rb+O_{2}\longrightarrow RbO_{2}} }">
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<annotation encoding="application/x-tex">{\displaystyle \mathrm {Rb+O_{2}\longrightarrow RbO_{2}} }</annotation>
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</math></span><img src="./_assets_/eb734a37dd21ce173a46342d1cc64c92/b8e924167872233f65455e74874590b312a1c673.svg" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:19.667ex; height:2.509ex;" alt="{\displaystyle \mathrm {Rb+O_{2}\longrightarrow RbO_{2}} }" loading="lazy"></span></dd></dl>
<div class="mw-heading mw-heading2"><h2 id="Eigenschaften">Eigenschaften</h2></div>
<p>Rubidiumhyperoxid ist ein oranger Feststoff und kristallisiert wie <a href="Kaliumhyperoxid" title="Kaliumhyperoxid">Kalium-</a> und <a href="Caesiumhyperoxid" title="Caesiumhyperoxid">Caesiumhyperoxid</a> in der <a href="Calciumcarbid" title="Calciumcarbid">Calciumcarbid</a>-Struktur.<sup id="cite_ref-Howi_4-1" class="reference"><a href="#cite_note-Howi-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>
Beim Erhitzen in einer <a href="Wasserstoff" title="Wasserstoff">Wasserstoff</a>atmosphäre bildet sich <a href="Rubidiumhydroxid" title="Rubidiumhydroxid">Rubidiumhydroxid</a>, Wasser und Sauerstoff, als Zwischenprodukt entsteht <a href="Wasserstoffperoxid" title="Wasserstoffperoxid">Wasserstoffperoxid</a>.<sup id="cite_ref-Erdmann_5-0" class="reference"><a href="#cite_note-Erdmann-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-JCS_6-0" class="reference"><a href="#cite_note-JCS-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup>
</p>
<dl><dd><span class="mwe-math-element mwe-math-element-inline"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle \mathrm {4\ RbO_{2}+4\ H_{2}\longrightarrow 4\ RbOH+2\ H_{2}O_{2}\longrightarrow 4\ RbOH+2\ H_{2}O+O_{2}} }">
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<annotation encoding="application/x-tex">{\displaystyle \mathrm {4\ RbO_{2}+4\ H_{2}\longrightarrow 4\ RbOH+2\ H_{2}O_{2}\longrightarrow 4\ RbOH+2\ H_{2}O+O_{2}} }</annotation>
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</math></span><img src="./_assets_/eb734a37dd21ce173a46342d1cc64c92/9b5ddb53808de575c1599aaf0e36eaf2560b8d84.svg" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -0.671ex; width:66.911ex; height:2.509ex;" alt="{\displaystyle \mathrm {4\ RbO_{2}+4\ H_{2}\longrightarrow 4\ RbOH+2\ H_{2}O_{2}\longrightarrow 4\ RbOH+2\ H_{2}O+O_{2}} }" loading="lazy"></span></dd></dl>
<p>Die <a href="Standardbildungsenthalpie" class="mw-redirect" title="Standardbildungsenthalpie">Standardbildungsenthalpie</a> von Rubidiumhyperoxid beträgt ΔH<sub>f</sub><sup>0</sup>&nbsp;=&nbsp;−288&nbsp;kJ/mol.<sup id="cite_ref-wiberg1_7-0" class="reference"><a href="#cite_note-wiberg1-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Literatur">Literatur</h2></div>
<ul><li>D. L. Kraus, A. W. Petrocelli: <cite style="font-style:italic">The thermal decomposition of Rubidium superoxide<sup>1</sup></cite>. In: <cite style="font-style:italic">The Journal of Physical Chemistry</cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>66</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em">&nbsp;</span>7</span>, 1.&nbsp;Juli 1962, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>1225–1227</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1021/j100813a003">10.1021/j100813a003</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumhyperoxid&amp;rft.atitle=The+thermal+decomposition+of+Rubidium+superoxide1&amp;rft.au=D.+L.+Kraus%2C+A.+W.+Petrocelli&amp;rft.date=1962-07-01&amp;rft.doi=10.1021%2Fj100813a003&amp;rft.genre=journal&amp;rft.issue=7&amp;rft.jtitle=The+Journal+of+Physical+Chemistry&amp;rft.pages=1225-1227&amp;rft.volume=66" style="display:none">&nbsp;</span></li></ul>
<div class="mw-heading mw-heading2"><h2 id="Weblinks">Weblinks</h2></div>
<div class="sisterproject" style="margin:0.1em 0 0 0;"><div class="noresize noviewer" style="display:inline-block; line-height:10px; min-width:1.6em; text-align:center;" aria-hidden="true" role="presentation"><span class="mw-default-size" typeof="mw:File"><span title="Commons"></span></span></div><b><span class=""><a class="external text" href="https://commons.wikimedia.org/wiki/Category:Rubidium_superoxide?uselang=de"><span lang="en">Commons</span>: Rubidiumhyperoxid</a></span></b>&nbsp;– Sammlung von Bildern, Videos und Audiodateien</div>
<div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2></div>
<ol class="references">
<li id="cite_note-webelements-1"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-webelements_1-0">a</a></sup> <sup><a href="#cite_ref-webelements_1-1">b</a></sup> <sup><a href="#cite_ref-webelements_1-2">c</a></sup> <sup><a href="#cite_ref-webelements_1-3">d</a></sup></span> <span class="reference-text"><a rel="nofollow" class="external text" href="http://www.webelements.com/compounds/rubidium/rubidium_superoxide.html">rubidium superoxide (Webelements)</a></span>
</li>
<li id="cite_note-brauer-2"><span class="mw-cite-backlink"><a href="#cite_ref-brauer_2-0">↑</a></span> <span class="reference-text"><a href="Georg_Brauer" title="Georg Brauer">Georg Brauer</a> (Hrsg.), unter Mitarbeit von <a href="Marianne_Baudler" title="Marianne Baudler">Marianne Baudler</a> u.&nbsp;a.: <i>Handbuch der Präparativen Anorganischen Chemie.</i> 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 957.</span>
</li>
<li id="cite_note-NV-3"><span class="mw-cite-backlink"><a href="#cite_ref-NV_3-0">↑</a></span> <span class="reference-text">Dieser Stoff wurde in Bezug auf seine Gefährlichkeit entweder noch nicht eingestuft oder eine verlässliche und zitierfähige Quelle hierzu wurde noch nicht gefunden.</span>
</li>
<li id="cite_note-Howi-4"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-Howi_4-0">a</a></sup> <sup><a href="#cite_ref-Howi_4-1">b</a></sup></span> <span class="reference-text"><a href="Arnold_F._Holleman" title="Arnold F. Holleman">A. F. Holleman</a>, <a href="Egon_Wiberg" title="Egon Wiberg">E. Wiberg</a>, <a href="Nils_Wiberg" title="Nils Wiberg">N. Wiberg</a>: <i><a href="Holleman-Wiberg_Lehrbuch_der_Anorganischen_Chemie" title="Holleman-Wiberg Lehrbuch der Anorganischen Chemie">Lehrbuch der Anorganischen Chemie</a>.</i> 102.&nbsp;Auflage. Walter de Gruyter, Berlin 2007, ISBN 978-3-11-017770-1, S.&nbsp;1285–1286.<span class="editoronly" style="display:none;"></span></span>
</li>
<li id="cite_note-Erdmann-5"><span class="mw-cite-backlink"><a href="#cite_ref-Erdmann_5-0">↑</a></span> <span class="reference-text">Hugo Erdmann, Paul Köthner: <cite style="font-style:italic">Ueber Rubidiumdioxyd</cite>. In: <cite style="font-style:italic">Justus Liebigs Annalen der Chemie</cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>294</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em">&nbsp;</span>1</span>, 1897, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>55–71</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1002/jlac.18972940103">10.1002/jlac.18972940103</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumhyperoxid&amp;rft.atitle=Ueber+Rubidiumdioxyd&amp;rft.au=Hugo+Erdmann%2C+Paul+K%C3%B6thner&amp;rft.date=1897&amp;rft.doi=10.1002%2Fjlac.18972940103&amp;rft.genre=journal&amp;rft.issue=1&amp;rft.jtitle=Justus+Liebigs+Annalen+der+Chemie&amp;rft.pages=55-71&amp;rft.volume=294" style="display:none">&nbsp;</span></span>
</li>
<li id="cite_note-JCS-6"><span class="mw-cite-backlink"><a href="#cite_ref-JCS_6-0">↑</a></span> <span class="reference-text">Zusammenfassung der Arbeit von Erdmann und Köthner in: <i>J. Chem. Soc.</i> 72, Nr. 2, 1897, S. 96 (<a rel="nofollow" class="external text" href="http://www.archive.org/stream/journalchemical01britgoog#page/n139/mode/1up">Volltext</a>).</span>
</li>
<li id="cite_note-wiberg1-7"><span class="mw-cite-backlink"><a href="#cite_ref-wiberg1_7-0">↑</a></span> <span class="reference-text"><a href="Arnold_F._Holleman" title="Arnold F. Holleman">A. F. Holleman</a>, <a href="Egon_Wiberg" title="Egon Wiberg">E. Wiberg</a>, <a href="Nils_Wiberg" title="Nils Wiberg">N. Wiberg</a>: <i><a href="Holleman-Wiberg_Lehrbuch_der_Anorganischen_Chemie" title="Holleman-Wiberg Lehrbuch der Anorganischen Chemie">Lehrbuch der Anorganischen Chemie</a>.</i> 101.&nbsp;Auflage. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9, S.&nbsp;1176.<span class="editoronly" style="display:none;"></span></span>
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